1,3-Phenyl­ene bis­{3-[2-chloro-4-(tri­fluoro­meth­yl)phen­oxy]benzoate}

نویسندگان

  • Hao Peng
  • Hongwu He
چکیده

In the title compound, C(34)H(18)Cl(2)F(6)O(6), one terminal trifluoro-methyl and one entire 2-chloro-4-(trifluoro-meth-yl)phenyl group are disordered with refined occupancy ratios of 0.715 (11):0.285 (11) and 0.517 (5):0.429 (5), respectively. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into ribbons propagating along the a-axis direction.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

6,6′-Dimeth­oxy-2,2′-[(E,E′)-(2,4,6-trimethyl-1,3-phenyl­ene)bis­(nitrilo­methanylyl­idene)]diphenol chloro­form monosolvate

In the title compound, C(25)H(26)N(2)O(4)·CHCl(3), the aromatic rings of the imino-methyl-6-meth-oxy-phenol fragments make dihedral angles of 58.33 (6) and 87.74 (6)° with the central benzene ring. The mol-ecular conformation is stabilized by intra-molecular O-H⋯N hydrogen bonds. In the crystal, an inter-molecular C-H⋯O hydrogen bond involving the chloro-form solvent mol-ecule is observed. The ...

متن کامل

N,N′-[(2,3,5,6-Tetra­methyl-p-phenyl­ene)dimethyl­ene]bis­[2-chloro-N-(2-chloro­ethyl)ethanamine]

The title mol-ecule, C(20)H(32)Cl(4)N(2), lies on an inversion center. A weak intra-molecular C-H⋯N hydrogen bond may, in part, influence the conformation of the mol-ecule.

متن کامل

Bis(2-amino-6-methyl-1,3-benzothia­zole-κN 3)bis­(4-nitro­benzoato-κO 1)zinc

In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia-zole and by two carboxylate O atoms from two 4-nitro-benzoate ligands, adopting a slightly distorted tetra-hedral coordination geometry. In the crystal, inter-molecular N-H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1...

متن کامل

catena-Poly[[bis­(5-chloro-2-nitro­benzoato)copper(II)]-bis­(μ-5-chloro-2-nitro­benzoato)]

In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxyl-ate groups of five 5-chloro-2-nitro-benzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, ...

متن کامل

Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)

In the title compound, [Pt(C17H19N4)Cl], the Pt(II) cation is C,C',C''-chelated by the 1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazolyl-idene) anion and coordinated by a Cl(-) anion in a distorted square-planar coordination geometry. π-π stacking is observed between nearly parallel imidazole and benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.802 (4) Å.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012